1.SYNTHESIS AND REACTIVITY OF CHROMIUM AND MANGANESE DIBROMOACETATES AND THEIR COMPLEXES WITH ORGANIC BASES By By JUGAL KISHORE PURI1 AND RAJNI CHHOKER2

Authors

  • JUGAL KISHORE PURI1 AND RAJNI CHHOKER2

Abstract

Complexes of composition CrCl(Br2CHCOO)2, Cr3O(Br2CHCOO)6Cl, [Cr3O(Br2CHCOO)6(Br2CHCOOH)3Cl], Cr(Br2CHCOO)3, Cr(Br2CHCOO)3.Py, Cr(Br2CHCOO)3.Q, Cr(Br2CHCOO)3(C2H5)3N, [Cr3O(Br2CHCOO)6(NH3)3]Cl.5NH3, Mn(Br2CHCOO)2, Mn(Br2CHCOO)2.2Py, Mn(Br2CHCOO)2.2Q, Mn(Br2CHCOO)2.2(C2H5)3N and (Me4N)2Mn(Br2CHCOO)4 have been synthesized. All these compounds have been characterized by elemental analysis, molar conductance, infra-red, reflectance and thermo-gravimetric studies. These studies indicate the hexa co-ordination of chromium and manganese in these compounds having octahedral geometry and suggest the formation of polymeric structures. Further attempts are in progress to isolate the single crystal of these complexes in order to throw more light on the structure of these complexes from single crystal x-ray studies.
KEY WORD: Chromium, Manganese, Dibromoacetates, spectroscopic techniques, TGA studies.

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Author Biography

JUGAL KISHORE PURI1 AND RAJNI CHHOKER2

SYNTHESIS AND REACTIVITY OF CHROMIUM AND MANGANESE DIBROMOACETATES AND THEIR COMPLEXES WITH ORGANIC BASES
JUGAL KISHORE PURI1 AND RAJNI CHHOKER2
1CENTRE OF ADVANCED STUDIES AND DEPARTMENT OF CHEMISTRY, PANJAB UNIVERSITY,
CHANDIGARH 160014, INDIA.
Email: prof_ jkpuri@yahoo.com

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Published

2015-04-01

How to Cite

RAJNI CHHOKER2, J. K. P. A. (2015). 1.SYNTHESIS AND REACTIVITY OF CHROMIUM AND MANGANESE DIBROMOACETATES AND THEIR COMPLEXES WITH ORGANIC BASES By By JUGAL KISHORE PURI1 AND RAJNI CHHOKER2. INTERNATIONAL RESEARCH JOURNAL OF CHEMISTRY, 9, 1 to 19. Retrieved from https://petsd.org/ojs/index.php/irjc/article/view/72