THERMODYNAMIC STUDY ON COMPLEXATION EQUILIBRIA OF UO2(II) BINARY WITH LACTIC ACID ACID SYSTEM
Coordination compounds differ greatly in nature and stability, so chemists could not completely agree on a simple definition of the term â€œCoordination Compoundâ€. Early workers in this field had a few of the modern physico-chemical tools at their disposal, and if a material satisfied the law of definite proportions, it was considered as a compound.
KEY WORD: Thermodynamic, Complexation, Equilibria, UO2(II), Binary,Â Lactic acid.
1. Bjerrum J.; Metal-ammine formation in aqueous solution; McGrawâ€“Hill, New Delhi, 322 (1941).
2. Ostwald, W., â€œZur Theorie der FlÃ¼ssigkeiten,â€ Z. Phys. Chem., 2, 36 (1888).
3. Dawson, H.M. and McCrae, J., â€œThe nature of metal-ammonia compounds in aqueous solution. Part Iâ€, J. Chem. Soc., Trans., 77, 1239-1262, (1900).
4. Bodlander, G., Z. Phys. Chem., 9, 770 (1882).
5. Irving, H.M. and Rossotti, H.S.; The calculation of formation curves of metal complexes from pH titration curves in mixed solvents; J. Chem. Soc., 2904 (1954).
6. Welchey, F. J.; The analytical use of ethylenediaminetetra acetic acid; Van Nostrand, Princeton, N.Y. (1965).
7. Flascka, H.; Mikrotitrationen with ethylenediaminetetraacetic acid. XIV, The determination of some rare earths; Mikrochim Acta., 55 (1955).Adenosine Triphosphate with metal Ions, J. chem. Soc., 5422 (1964).